A Reactive Manganese(IV)–Hydroxide Complex: A Missing Intermediate in Hydrogen Atom Transfer by High-Valent Metal-Oxo Porphyrinoid Compounds
نویسندگان
چکیده
منابع مشابه
Electrocatalytic water oxidation by a molecular cobalt complex through a high valent cobalt oxo intermediate.
Biuret-modified tetraamidomacrocyclic cobalt complex [CoIII-bTAML]- is shown to catalyze electrochemical water oxidation at basic pH leading to the formation of O2. Electrochemical and spectroscopic studies indicate a high valent cobalt oxo intermediate isoelectronic to CoV(O) as the active oxidant. The kinetic isotope effect of 8.63 indicates an atom proton transfer mechanism.
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2018
ISSN: 0002-7863,1520-5126
DOI: 10.1021/jacs.8b00350